Abstract
The title compound, [Fe(CF3O3S)(C48H36N4O4)], is a five-coordinate iron(III) porphyrin complex with a trifluoromethanesulfonate anion as an axial ligand. The FeIII atom is displaced by 0.40 (1) Å towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe—Np distance is 2.044 (2) Å and the Fe—O distance is 2.001 (2) Å.
Highlights
The title compound, [Fe(CF3O3S)(C48H36N4O4)], is a fivecoordinate iron(III) porphyrin complex with a trifluoromethanesulfonate anion as an axial ligand
The authors are grateful to the National Institutes of Health (GM 064476 to GBR-A) and to the National Science Foundation (CHE-0911537 to GBR-A) for funds to conduct the research, and to the National Science Foundation (CHE0130835) and the University of Oklahoma for funds to acquire the diffractometer and computers used in this work
We report the structure of the five-coordinate compound (5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinato)iron(III)
Summary
The title compound, [Fe(CF3O3S)(C48H36N4O4)], is a fivecoordinate iron(III) porphyrin complex with a trifluoromethanesulfonate anion as an axial ligand. [5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato-j4N,N0 ,N0 0 ,N0 0 0 ](trifluoromethanesulfonato-jO)iron(III) Absorption correction: multi-scan (SADABS; Sheldrick, 2001) The FeIII atom is displaced by 0.40 (1) Å towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin.
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