Abstract

The title compound, [Hg(C7H5O2)(C12H27O3SSi)], was obtained by the reaction of 4-hydroxy­mercurio­benzoic acid with tri-tert-butoxy­silane­thiol. There are two independent mol­ecules in the asymmetric unit, which are linked by hydrogen bonds involving the carboxyl­ic acid groups. Two heterocubane-like Hg4S4 supramolecular arrangements are formed by weak Hg⋯S interactions.

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