4f-band magnetism in CeFe2.

Abstract

We explain the anomaly in the lattice constants of the series Ce${\mathrm{Fe}}_{2}$-Ce${\mathrm{Ni}}_{2}$ quantitatively in terms of $3d\ensuremath{-}4f$ hybridization rather than a valence change. Ce${\mathrm{Fe}}_{2}$ is calculated to be magnetic and is the first Ce compound for which self-consistent energy-band calculations yield the correct total moment (${2.4}_{\mathrm{\ensuremath{\mu}}\mathrm{B}}$/formula unit) including a contribution of ${\ensuremath{-}0.4}_{\mathrm{\ensuremath{\mu}}\mathrm{B}}$ from the $4f$ electrons. The calculated magnetization density and spin-resolved density of states, which are unique to itinerant-electron theory, may be verified in detail by magnetic form-factor and spin-polarized photoemission measurements.