Abstract
In the title compound, C12H10BrN, the dihedral angle between the benzene rings is 52.5 (1)°, whereas the pitch angles, or the angles between the mean plane of each aryl group ‘propeller blade’ and the plane defined by the aryl bridging C—N—C angle, are 19.6 (2) and 36.2 (3)°. While the N—H group is not involved in hydrogen-bonding interactions, the structure exhibits a network of intermolecular C—H⋯π and N—H⋯π interactions.
Highlights
C12H10BrN, the dihedral angle between the benzene rings is 52.5 (1), whereas the pitch angles, or the angles between the mean plane of each aryl group ‘propeller blade’ and the plane defined by the aryl bridging C—N—C angle, are 19.6 (2) and 36.2 (3)
While the N—H group is not involved in hydrogen-bonding interactions, the structure exhibits a network of intermolecular C—HÁ Á Á and N— HÁ Á Á interactions
Related literature The title compound is an amine analogue of brominated diphenyl ether flame retardant materials commonly used in household items
Summary
C12H10BrN, the dihedral angle between the benzene rings is 52.5 (1), whereas the pitch angles, or the angles between the mean plane of each aryl group ‘propeller blade’ and the plane defined by the aryl bridging C—N—C angle, are 19.6 (2) and 36.2 (3). While the N—H group is not involved in hydrogen-bonding interactions, the structure exhibits a network of intermolecular C—HÁ Á Á and N— HÁ Á Á interactions. Related literature The title compound is an amine analogue of brominated diphenyl ether flame retardant materials commonly used in household items. For information on environmental and health concerns related to brominated flame retardants, see: de Wit (2002); Lunder et al (2010). For a related structure and information on C—HÁ Á Á and N—HÁ Á Á interactions, see: Krzyminski et al (2009). For a description of the pitch angle in similar diphenyl structures, see: Duong & Tanski (2011); Lim & Tanski (2007)
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