Abstract
The reaction of 4-bromoaniline, 18-crown-6, and perchloric acid in methanol yields the title compound, C6H7BrN+·ClO4 −·C12H24O6, in which the protonated –NH3 + group forms three bifurcated N—H⋯O hydrogen bonds to the O atoms of the crown ether.
Highlights
Ordered Matter Science Research Center, College of Chemistry and Chemical, Engineering, Southeast University, Nanjing 211189, People’s Republic of China
Supplementary data and figures for this paper are available from the IUCr electronic archives
The title compound is composed of cationic [C6BrNH7(18-Crown-6)]+
Summary
Ordered Matter Science Research Center, College of Chemistry and Chemical, Engineering, Southeast University, Nanjing 211189, People’s Republic of China. Key indicators: single-crystal X-ray study; T = 93 K; mean (C–C) = 0.003 Å; R factor =. 0.038; wR factor = 0.104; data-to-parameter ratio = 18.5. The reaction of 4-bromoaniline, 18-crown-6, and perchloric acid in methanol yields the title compound, C6H7BrN+ClO4C12H24O6, in which the protonated –NH3+ group forms three bifurcated N—H O hydrogen bonds to the O atoms of the crown ether
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