Abstract

In the title compound, C19H15N3O3, the anilino and benzamide rings make dihedral angles of 10.66 (16) and 50.39 (16)°, respectively, with the nitro-substituted benzene ring. The nitro group is slightly twisted by 11.49 (17)° with respect to the attached benzene ring. There is an intra­molecular N—H⋯O hydrogen bond forming an S(6) ring. In the crystal, weak inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a chain parallel to the b axis. Futhermore, weak slipped π–π inter­actions [centroid–centroid distance = 3.819 (2) Å, inter­planar distance = 3.567 Å and offset angle [how is the offset angle defined?] = 21°] between the anilino ring and its symmetry-related counterpart may help to stabilize the packing.

Highlights

  • Crystal dataGuihua Chena* and Jian Yanb a School of Pharmaceutical and Chemical Engineering, Taizhou University, Linhai

  • In the title compound, C19H15N3O3, the anilino and benzamide rings make dihedral angles of 10.66 (16) and 50.39 (16), respectively, with the nitro-substituted benzene ring

  • Whereas weak intermolecular N-H···O and C-H···O hydrogen bonds link the molecules into a chain parallel to the b axis (Table 1, Fig. 2)

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Summary

Crystal data

Guihua Chena* and Jian Yanb a School of Pharmaceutical and Chemical Engineering, Taizhou University, Linhai. Consulting Co. Ltd, Taizhou University, Ningbo 315010, People’s Republic of China. C19H15N3O3, the anilino and benzamide rings make dihedral angles of 10.66 (16) and 50.39 (16) , respectively, with the nitro-substituted benzene ring. The nitro group is slightly twisted by 11.49 (17) with respect to the attached benzene ring. There is an intramolecular N—H O hydrogen bond forming an S(6) ring. Weak intermolecular N—H O and C—H O hydrogen bonds link the molecules into a chain parallel to the b axis. Futhermore, weak slipped – interactions [centroid–centroid distance = 3.819 (2) Å, interplanar distance = 3.567 Å and offset angle [how is the offset angle defined?] = 21 ] between the anilino ring and its symmetry-related counterpart may help to stabilize the packing

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Guihua Chen and Jian Yan
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