Abstract
In the title compound, C19H15N3O3, the anilino and benzamide rings make dihedral angles of 10.66 (16) and 50.39 (16)°, respectively, with the nitro-substituted benzene ring. The nitro group is slightly twisted by 11.49 (17)° with respect to the attached benzene ring. There is an intramolecular N—H⋯O hydrogen bond forming an S(6) ring. In the crystal, weak intermolecular N—H⋯O and C—H⋯O hydrogen bonds link the molecules into a chain parallel to the b axis. Futhermore, weak slipped π–π interactions [centroid–centroid distance = 3.819 (2) Å, interplanar distance = 3.567 Å and offset angle [how is the offset angle defined?] = 21°] between the anilino ring and its symmetry-related counterpart may help to stabilize the packing.
Highlights
Crystal dataGuihua Chena* and Jian Yanb a School of Pharmaceutical and Chemical Engineering, Taizhou University, Linhai
In the title compound, C19H15N3O3, the anilino and benzamide rings make dihedral angles of 10.66 (16) and 50.39 (16), respectively, with the nitro-substituted benzene ring
Whereas weak intermolecular N-H···O and C-H···O hydrogen bonds link the molecules into a chain parallel to the b axis (Table 1, Fig. 2)
Summary
Guihua Chena* and Jian Yanb a School of Pharmaceutical and Chemical Engineering, Taizhou University, Linhai. Consulting Co. Ltd, Taizhou University, Ningbo 315010, People’s Republic of China. C19H15N3O3, the anilino and benzamide rings make dihedral angles of 10.66 (16) and 50.39 (16) , respectively, with the nitro-substituted benzene ring. The nitro group is slightly twisted by 11.49 (17) with respect to the attached benzene ring. There is an intramolecular N—H O hydrogen bond forming an S(6) ring. Weak intermolecular N—H O and C—H O hydrogen bonds link the molecules into a chain parallel to the b axis. Futhermore, weak slipped – interactions [centroid–centroid distance = 3.819 (2) Å, interplanar distance = 3.567 Å and offset angle [how is the offset angle defined?] = 21 ] between the anilino ring and its symmetry-related counterpart may help to stabilize the packing
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