4-Amino-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide–4-nitrobenzoic acid (1/1)

Abstract

In the asymmetric unit of the title co-crystal, C7H5NO4·C12H14N4O2S, there are two independent but conformationally similar heterodimers, which are formed through inter­molecular N—H⋯Ocarb­oxy and carbox­yl–pyrimidine O—H⋯N hydrogen-bond pairs, giving a cyclic motif [graph set R 2 2(8)]. The dihedral angles between the rings in the sulfonamide molecules are 78.77 (8) and 82.33 (9)° while the dihedral angles between the ring and the CO2H group in the acids are 2.19 (9) and 7.02 (10)°. A two-dimensional structure parallel to the ab plane is generated from the heterodimer units through hydrogen-bonding associations between NH2 and sulfone groups. Between neighbouring two-dimensional arrays there are two types of aromatic π–π stacking inter­actions involving either one of the pyrimidine rings and a 4-nitro­benzoic acid mol­ecule [minimum ring centroid separation = 3.5886 (9) Å] or two acid mol­ecules [minimum ring centroid separation = 3.7236 (10) Å].