Abstract
In the mononuclear title complex, [CuI(C6H8N2S)(C18H15P)2], the CuI ion is in a slightly distorted tetrahedral coordination geometry formed by two P atoms from two triphenylphosphane ligands, one S atom from a 4,6-dimethylpyrimidine-2(1H)-thione ligand and one iodide ion. There is an intramolecular N—H⋯I hydrogen bond. In the crystal, π–π stacking interactions [centroid–centroid distance = 3.594 (1) Å] are observed.
Highlights
H atoms treated by a mixture of independent and constrained refinement max = 0.90 e Å 3
In the mononuclear title complex, [CuI(C6H8N2S)(C18H15P)2], the CuI ion is in a slightly distorted tetrahedral coordination geometry formed by two P atoms from two triphenylphosphane ligands, one S atom from a 4,6-dimethylpyrimidine-2(1H)-thione ligand and one iodide ion
H atoms treated by a mixture of independent and constrained refinement w = 1/[σ2(Fo2) + (0.040P)2 + 0.4017P]
Summary
Patcharanan Chotoa and Ruthairat Nimthonga a Department of Chemistry and Center for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand, and b Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai R factor = 0.028; wR factor = 0.075; data-to-parameter ratio = 20.9.
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