Abstract
In the the title compound, C27H23ClN4O2, the chlorophenyl ring forms dihedral angles of 77.70 (9) and 86.65 (9)°, respectively, with the pyrazol-3-one and pyrazole rings. The phenyl rings attached to the pyrazole rings are twisted away from them [dihedral angles 33.80 (9) and 40.34 (10)°]. An intramolecular O—H⋯O hydrogen bond generates an S(8) ring motif. The molecules are linked into chains running along the c axis by N—H⋯N hydrogen bonds, and the chains are cross-linked via C—H⋯O hydrogen bonds and C—H⋯π interactions involving the chlorophenyl ring.
Highlights
In the the title compound, C27H23ClN4O2, the chlorophenyl ring forms dihedral angles of 77.70 (9) and 86.65 (9), respectively, with the pyrazol-3-one and pyrazole rings
The phenyl rings attached to the pyrazole rings are twisted away from them [dihedral angles 33.80 (9) and 40.34 (10)]
The molecules are linked into chains running along the c axis by N—HÁ Á ÁN hydrogen bonds, and the chains are cross-linked via C—HÁ Á ÁO hydrogen bonds and C—HÁ Á Á interactions involving the chlorophenyl ring
Summary
Absorption correction: multi-scan (SADABS; Bruker, 2005) Tmin = 0.923, Tmax = 0.987. R[F 2 > 2(F 2)] = 0.054 wR(F 2) = 0.121 S = 1.02 6751 reflections 317 parameters 2 restraints. In the the title compound, C27H23ClN4O2, the chlorophenyl ring forms dihedral angles of 77.70 (9) and 86.65 (9), respectively, with the pyrazol-3-one and pyrazole rings. The phenyl rings attached to the pyrazole rings are twisted away from them [dihedral angles 33.80 (9) and 40.34 (10)]. An intramolecular O—HÁ Á ÁO hydrogen bond generates an S(8) ring motif. The molecules are linked into chains running along the c axis by N—HÁ Á ÁN hydrogen bonds, and the chains are cross-linked via C—HÁ Á ÁO hydrogen bonds and C—HÁ Á Á interactions involving the chlorophenyl ring
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
