Abstract
In the title compound, [Sn(C6H5)3(C14H9N2O4)], the Sn atom has a distorted tetrahedral geometry with one of the carboxylate O atoms and the C atoms from three phenyl groups. The other carboxylate O atom of the benzoate ligand interacts weakly with the Sn atom, with an Sn⋯O distance of 2.790 (2) Å, which causes a distortion of the tetrahedral coordination geometry.
Highlights
In the title compound, [Sn(C6H5)3(C14H9N2O4)], the Sn atom has a distorted tetrahedral geometry with one of the carboxylate O atoms and the C atoms from three phenyl groups
The other carboxylate O atom of the benzoate ligand interacts weakly with the Sn atom, with an SnÁ Á ÁO distance of 2.790 (2) A, which causes a distortion of the tetrahedral coordination geometry
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: IS2569)
Summary
Key indicators: single-crystal X-ray study; T = 296 K; mean (C–C) = 0.005 A; R factor = 0.034; wR factor = 0.058; data-to-parameter ratio = 13.9. In the title compound, [Sn(C6H5)3(C14H9N2O4)], the Sn atom has a distorted tetrahedral geometry with one of the carboxylate O atoms and the C atoms from three phenyl groups. The other carboxylate O atom of the benzoate ligand interacts weakly with the Sn atom, with an SnÁ Á ÁO distance of 2.790 (2) A , which causes a distortion of the tetrahedral coordination geometry. Related literature For related literature on organotin carboxylates, see: Basu Baul et al (1996, 2004). See: Basu Baul et al (2006). Crystal data [Sn(C6H5)3(C14H9N2O4)] Mr = 619.22 Monoclinic, P21=c a = 8.3751 (2) Ab = 48.8458 (11) Ac = 6.9742 (2) A = 97.262 (1)
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