Abstract
AbstractThe construction of C—C and C—X bonds via cross-dehydrogenative coupling (CDC) reactions has made remarkable progress, and the methods developed have reached excellent levels of versatility, selectivity, and efficiency over the past few decades. The oxidative coupling of various C—H or X—H substrates to terminal alkynes can complement the coupling reactions of functionalized starting materials and can minimize waste and allow faster access to functionalized product molecules. These reactions represent a historic breakthrough in alkynylation chemistry and have greatly expanded the synthetic routes available for the efficient construction of alkynyl compounds.
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