Abstract

The 4-oxocyclohexa-2,5-dienylidenes are an interesting class of highly electrophilic carbenes. We investigated the reactivity of the 2,3,5,6-tetrafluorinated and -tetrachlorinated derivatives 1 b and 1 c with small molecules under conditions of matrix isolation. The reactions with molecular oxygen and with carbon monoxide produce the expected carbonyl O-oxides and ketenes, respectively. As a result of the extreme electrophilicity of 1 b and c both carbenes insert with no or very small activation barriers into H2 or the CH bonds of hydrocarbons. Obviously, spin restrictions for these formally spin-forbidden reactions do not result in substantial thermal activation barriers.

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