4-(o-Tol-yl)piperazin-1-ium chloride.

Hoong-Kun Fun,Safra Izuani Jama Asik,Arun M Isloor,Prakash Shetty,B Chandrakantha

doi:10.1107/s1600536811044394

Abstract

In the title molecular salt, C11H17N2 +·Cl−, the piperazin-1-ium ring adopts a chair conformation with the aromatic ring in a pseudo-equatorial orientation. The dihedral angle between the benzene ring and the mean plane of the piperazin-1-ium ring is 51.22 (6)°. In the crystal, N—H⋯Cl hydrogen bonds link the molecules into chains propagating in [100]. Weak C—H⋯π interactions also ocur.

Highlights

In the title molecular salt, C11H17N2+Cl, the piperazin-1-ium ring adopts a chair conformation with the aromatic ring in a pseudo-equatorial orientation
N—H Cl hydrogen bonds link the molecules into chains propagating in [100]
Symmetry codes: (i) x+1, y+1, z+1; (ii) x+1/2, −y+3/2, −z+1; (iii) −x+3/2, −y+2, z+1/2

Summary

Data collection

USM, Penang, Malaysia, bDepartment of Chemistry, Manipal Institute of Technology, Manipal 576 104, India., cMedicinal Chemistry Division, Department of Chemistry, National Institute of Technology-Karnataka, Surathkal, Mangalore, 025, India., and dDepartment of Printing, Manipal Institute of Technology, Manipal 104, India

Bruker APEX DUO CCD diffractometer

Related literature

Crystal data

Special details