Abstract
In the structure of the title compound, C7H7IN2O, the hydrazide group is inclined at 13.3 (3)° with respect to the benzene ring. The structure is stabilized by intermolecular N—H⋯N and N—H⋯O hydrogen bonds involving the hydrazide group, resulting in six- and ten-membered rings with R 2 2(6) and R 2 2(10) graph-set notations, respectively.
Highlights
In the structure of the title compound, C7H7IN2O, the hydrazide group is inclined at 13.3 (3) with respect to the benzene ring
The structure is stabilized by intermolecular N— HÁ Á ÁN and N—HÁ Á ÁO hydrogen bonds involving the hydrazide group, resulting in six- and ten-membered rings with R22(6) and R22(10) graph-set notations, respectively
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: PV2109)
Summary
Key indicators: single-crystal X-ray study; T = 296 K; mean (C–C) = 0.006 A; R factor = 0.029; wR factor = 0.106; data-to-parameter ratio = 19.0. In the structure of the title compound, C7H7IN2O, the hydrazide group is inclined at 13.3 (3) with respect to the benzene ring. The structure is stabilized by intermolecular N— HÁ Á ÁN and N—HÁ Á ÁO hydrogen bonds involving the hydrazide group, resulting in six- and ten-membered rings with R22(6) and R22(10) graph-set notations, respectively. Related literature For related structures, see: Kallel et al (1992); Saraogi et al (2002); Ashiq, Jamal et al (2008). See: Ara et al (2007); Ashiq, Ara et al (2008); Bernstein et al (1994)
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