Abstract
In the title compound, C10H9ClN4S, the dihedral angle between the mean planes of the phenyl and 1H-1,2,4-triazole-5(4H)-thione rings is 25.3 (9)°. The latter ring is essentially planar, with maximum deviations of 0.010 and −0.010 Å for the ring N atom in the 4-position and ring C atom bearing the methyl group, respectively. An intramolecular C—H⋯S contact occurs. In the crystal, pairs of weak N—H⋯S interactions link the molecules into inversion dimers in the ac plane, forming R 2 2(8) graph-set motifs. In addition, weak π–π interactions [centroid–centroid distances = 3.3463 (14) and 3.6127 (13)Å] are observed.
Highlights
In the title compound, C10H9ClN4S, the dihedral angle between the mean planes of the phenyl and 1H-1,2,4triazole-5(4H)-thione rings is 25.3 (9)
For the crystal structures of Schiff bases reported by our group, see: Sarojini et al (2007a,b)
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)
Summary
College of Engineering, Nadupadavu 574 153, D.K., Mangalore, India, bDepartment of Studies in Chemistry, Mangalore University, Mangalagangotri 574 199, Mangalore, India, cDepartment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India, and dDepartment of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA
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