Abstract
In the title compound, C14H12ClNO3S, the conformation of the N—H bond in the C—SO2—NH—C(O) segment is anti to the C=O bond. The two aromatic rings are tilted relative to each other by 57.7 (1)°. In the crystal, molecules are linked by pairs of N—H⋯O(S) hydrogen bonds, forming centrosymmetric dimers.
Highlights
Molecules are linked by pairs of N—H O(S) hydrogen bonds, forming centrosymmetric dimers
The molecules are twisted at the S atom with the torsional angle of -69.2 (2)°, compared to those of 65.7 (2)° in (II), 67.7 (2)° in (III) and -64.0 (2)° in (IV)
The dihedral angles between the sulfonyl benzene ring and the —SO2—NH—C—O segment is 87.2 (1)°, compared to the values of 88.5 (1)° in (II), 87.1 (1)° in (III) and 88.4 (1)° in (IV)
Summary
Department of Chemistry, Mangalore University, Mangalagangotri 574 199, Mangalore, India, and bInstitute of Materials Science, Darmstadt University of Technology, Petersenstrasse 23, D-64287 Darmstadt, Germany H atoms treated by a mixture of independent and constrained refinement max = 0.76 e Å3 R factor = 0.052; wR factor = 0.147; data-to-parameter ratio = 13.5. Hydrogen-bond geometry (Å, ). C O bond. The two aromatic rings are tilted relative to each other by 57.7 (1) . In the crystal, molecules are linked by pairs of N—H O(S) hydrogen bonds, forming centrosymmetric dimers.
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
