Abstract
The title complex, [Nd(C15H11O2)(NO3)2(C18H15N3O)]·CH3CN or [Nd(altpy)(dbm)(NO3)2]·CH3CN (altpy = 4′-allyloxy-2,2′:6′,2′′-terpyridine, dbm = dibenzoylmethanide anion), has been synthesized from 4′-allyloxy-2,2′:6′,2′′-terpyridine, dibenzoylmethanate and neodymium nitrate. The Nd3+ atom is nine-coordinated by two O atoms from the bidentate dbm ligand, three N atoms from the tridentate altpy ligand and four O atoms from two nitrate anions that act as bidentate ligands and occupy mutually trans sites in a distorted monocapped square-antiprismatic geometry.
Highlights
The title complex, [Nd(C15H11O2)(NO3)2(C18H15N3O)]CH3CN or [Nd(altpy)(dbm)(NO3)2]CH3CN, has been synthesized from 40 -allyloxy-2,20 :60,200 -terpyridine, dibenzoylmethanate and neodymium nitrate
The Nd3+ atom is nine-coordinated by two O atoms from the bidentate dbm ligand, three N atoms from the tridentate altpy ligand and four
O atoms from two nitrate anions that act as bidentate ligands and occupy mutually trans sites in a distorted monocapped square-antiprismatic geometry
Summary
Jiangsu Key Laboratory of Organic Electronics and Information Displays, and Institute of Advanced Materials (IAM), Nanjing University of Post and Telecommunications, Nanjing 210046, People’s Republic of China, and bInstitute of Molecular. R factor = 0.029; wR factor = 0.069; data-to-parameter ratio = 14.2. The title complex, [Nd(C15H11O2)(NO3)2(C18H15N3O)]CH3CN or [Nd(altpy)(dbm)(NO3)2]CH3CN (altpy = 40 -allyloxy-2,20 :60 ,200 -terpyridine, dbm = dibenzoylmethanide anion), has been synthesized from 40 -allyloxy-2,20 :60 ,200 -terpyridine, dibenzoylmethanate and neodymium nitrate. The Nd3+ atom is nine-coordinated by two O atoms from the bidentate dbm ligand, three N atoms from the tridentate altpy ligand and four. O atoms from two nitrate anions that act as bidentate ligands and occupy mutually trans sites in a distorted monocapped square-antiprismatic geometry
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