Abstract

The partition of tracer-level (<10−7 mole/l) platinum between various 4-(5-nonyl)-pyridine phases and aqueous nitric, hydrochloric, and sulphuric acid phases has been studied radiometrically as a function of the amine and acid concentrations. The effects of saltingout agents and some anions on the extraction of the metal are reported. The extraction data is compared with that of gold and conditions are established for the separation of daughter199Au from neutron irradiated platinum. The distribution coefficients of various metal ions are given for the 4-(5-nonyl)pyridine-10M HCl system and their factors for separation from platinum estimated.

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