Abstract
A [3+2]-cycloaddition toward bishydroxymethyl-1,2,3-triazole makes the title compound available through selective nitration. The obtained sensitive 2-nitrotriazole was shown to have a high density of 1.764 g cm-3 and a detonation velocity of 8590 m s-1. It can also be classified as an oxidizer with an oxygen balance toward CO of 12%. Further representatives of this rare class of 2-nitro-1,2,3-triazoles were synthesized. One- and two-dimensional 15N NMR spectroscopy, crystal structure, and elemental analysis were performed.
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