Abstract

In the title compound, [Cu(C12H18N2O2)]·0.25H2O, the coordination of the O,N,N′,O′-tetra­dentate ligand results in a cis-CuN2O2 square-planar geometry for the metal ion and the presence of two six-membered and one five-membered chelate rings. The complete complex mol­ecule is close to planar (r.m.s. deviation = 0.047 Å). The uncoordinated water mol­ecule (O-atom site symmetry 2) was modelled as half occupied. In the crystal, C—H⋯Ow and Ow—H⋯O (w = water) hydrogen bonds link the components into layers parallel to ab plane.

Highlights

  • In the title compound, [Cu(C12H18N2O2)]0.25H2O, the coordination of the O,N,N0,O0 -tetradentate ligand results in a cis-CuN2O2 square-planar geometry for the metal ion and the presence of two six-membered and one five-membered chelate rings

  • H atoms treated by a mixture of independent and constrained refinement max = 0.56 e Å3

  • Water) hydrogen bonds link the components into layers parallel to ab plane

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Summary

Structure Reports

Pakistan Council of Scientific and Industrial Research Laboratories Complex, Karachi. 75280, Pakistan, bDepartment of Chemistry, University of Karachi, Karachi 75270, Pakistan, cDepartment of Chemistry, GC University, Faisalabad, Pakistan, d

Bruker Kappa APEXII CCD diffractometer
Related literature
MA expresses his gratitude to the PCSIR Laboratories
Nadeem Arshad
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