Abstract
In the title co-crystal, C10H8N2·C8H7NO4S, the formate group is coplanar with the pyridyl ring of the acid [dihedral angle = 6.2 (7)°], while the carboxymethylsulfanyl group makes a C—S—C—C torsion angle of 70.2 (1)° with the pyridine ring. The dihedral angle between the pyridyl rings of the 4,4′-bipyridine molecule is 27.4 (1)°. The acid and the 4,4′-bipyridine molecules are involved in hydrogen bonding via carboxylic O and pyridyl N atoms. The structure is further consolidated by intermolecular C—H⋯O hydrogen bonds, generating a three-dimensional network.
Highlights
Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People’s
In the title co-crystal, C10H8N2C8H7NO4S, the formate group is coplanar with the pyridyl ring of the acid [dihedral angle =
The structure is further consolidated by intermolecular C—H O hydrogen bonds, generating a three-dimensional network
Summary
R factor = 0.038; wR factor = 0.144; data-to-parameter ratio = 16.3. H atoms treated by a mixture of independent and constrained refinement max = 0.27 e Å3. In the title co-crystal, C10H8N2C8H7NO4S, the formate group is coplanar with the pyridyl ring of the acid [dihedral angle =. S—C—C torsion angle of 70.2 (1) with the pyridine ring. The dihedral angle between the pyridyl rings of the 4,40 -bipyridine molecule is 27.4 (1). The acid and the 4,40 -bipyridine molecules are involved in hydrogen bonding via carboxylic. The structure is further consolidated by intermolecular C—H O hydrogen bonds, generating a three-dimensional network
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
