3D-printing self-healing composite polymer reinforced with carbon nanotubes

Abstract

EMAA copolymer neutralized with sodium salt is a type of ionomer with self-healing abilities. This polymer has been used as raw material for the manufacturing of nanocomposite material by the addition of multiwall carbon nanotubes (MWCNTs). The optimization of the extrusion process, as well as the mixing and dispersion of the nano-reinforcement in the polymeric matrix during extrusion, deals with the manufacturing of a homogeneous reinforced filament. The obtained filaments were used afterwards as feeding materials of a 3D polymer printing machine and tensile test samples were manufactured. Mechanical properties of both unreinforced and reinforced samples were tested. The MWCNTs-reinforced samples exhibited higher mechanical properties without affecting its self-healing ability.