3D printed miniature atomic emission detector coupling with gas chromatography: A sensitive and cost-effective strategy for the determination of volatile methylsiloxanes in municipal sewage

Abstract

The determination of volatile methylsiloxanes (VMSs) in municipal sewage has attracted great attention. Gas chromatography-mass spectrometry (GC-MS) is the most mature detection technique for VMSs, however, its instrumentation and operation cost are unfavorable in low- and middle-income countries. Herein, a novel and cost-effective strategy by using a 3D printed miniature microplasma optical emission detector (μAED) as an alternative to MS detector, was developed to detect VMSs in municipal sewage by GC after preconcentration by a laboratory-built automatic purge and trap (P&T) system. Two types of μAEDs have been fabricated and their analytical performances were compared. The one using two tungsten rods as electrodes shows better performance and was thus selected as the detecting system for real sample analysis. Under the optimized conditions, the P&T-GC-μAED system provided limits of detection of 3.6 ng L−1 to 15.5 ng L−1 of Si for tested VMSs. Relative standard deviations were better than 3.0% and good recoveries ranging from 82.4% to 102.8% were obtained for all analytes. The applicability of this system was demonstrated via the measurement of VMSs in the influents and effluents from 10 wastewater treatment plants (WWTPs) in Chengdu, China.