Abstract
By control of mixed ligands with particular coordination sites, heterometallic coordination polymers, [Ln 2(H 2O) 2Ag(C 2O 4) 2(ina) 3] n (Ln = Eu ( 1), Dy ( 2), Hina = isonicotinic acid) and {[LnAg(C 2O 4)(na) 2]·2H 2O} n (Ln = La ( 3), Tb ( 4), Hna = nicotinic acid), have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, thermogravimetric analysis (TGA), and single-crystal X-ray diffraction. These coordination polymers feature 3D pillar-layered coordination frameworks constructed from two-dimensional (2D) lanthanide–carboxylate layers and Ag(ina) or Ag(na) pillars. It is interesting that the in situ decarboxylation of pyridine-2,3-dicarboxylic acid into nicotinic acid was observed. The luminescent properties of 1 and 4 were also studied.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
