製銅に関する物理化学的研究（第3報）熔銅とCO-CO<SUB>2</SUB>-SO<SUB>2</SUB>混合ガスとの平衡

Abstract

In the previous papers, we reported that te relation between the activity and the concentration of oxygen in liquid copper represented the negative deviation from Henry’s law. In the present paper, the equilibria between liquid copper and CO-CO2-SO2 gas mixtures have been measured. The reactions and their equilibrium constants may be expressed as follows:(This article is not displayable. Please see full text pdf.) \ oindentFrom the experimental results, it is found that K0′ and K′S diminish with an increase of the sulphur content.