Abstract
In the title compound, C31H29ClN2O2S, the pyrrolidine ring adopts an envelope conformation with the methine C atom adjacent to the NH group as the flap atom. The tetrahydropyridine ring has a half-chair conformation. The two rings are trans-fused. The chlorobenzene ring and the adjacent phenyl ring form a dihedral angle of 77.9 (1)°. The benzyl phenyl and the tosyl phenyl rings are oriented at a dihedral angle of 88.0 (1)°. In the crystal, molecules are linked into chains along the a axis by N—H⋯Cl and C—H⋯Cl hydrogen bonds and the adjacent chains are cross-linked via C—H⋯π interactions.
Highlights
In the title compound, C31H29ClN2O2S, the pyrrolidine ring adopts an envelope conformation with the methine C atom adjacent to the NH group as the flap atom
The benzyl phenyl and the tosyl phenyl rings are oriented at a dihedral angle of
Molecules are linked into chains along the a axis by N—H Cl and C—H Cl hydrogen bonds and the adjacent chains are cross-linked via C—H interactions
Summary
600 025, India, and cX-ray Crystallography Unit, School of Physics, Universiti Sains
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