3-Benzyl-2-phenyl-1,3-thia-zolidin-4-one.

Hoong-Kun Fun,Poovan Shanmugavelan,Madhukar Hemamalini,Alagusundaram Ponnuswamy,Rathinavel Jagatheesan

doi:10.1107/s1600536811037706

Hoong-Kun Fun, Poovan Shanmugavelan + Show 3 more

Open Access

https://doi.org/10.1107/s1600536811037706

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Abstract

In the title compound, C16H15NOS, the thiazolidine ring, which is essentially planar [maximum deviation = 0.071 (2) Å], makes dihedral angles of 88.01 (8) and 87.21 (8)° with the terminal phenyl rings. The dihedral angle between the phenyl rings is 49.45 (5)°. In the crystal, molecules are linked by a weak intermolecular C—H⋯O hydrogen bond, forming a supramolecular chain along the b axis. Furthermore, the crystal packing is stabilized by a weak C—H⋯π interaction.

Highlights

In the title compound, C16H15NOS, the thiazolidine ring, which is essentially planar [maximum deviation = 0.071 (2) Å], makes dihedral angles of 88.01 (8) and 87.21 (8) with the terminal phenyl rings
Cg1 is the centroid of the C11–C16 ring
Molecules are linked by a weak intermolecular C—H O hydrogen bond, forming a supramolecular chain along the b axis

Summary

Data collection

USM, Penang, Malaysia, bDepartment of Organic Chemistry, School of Chemistry, Madurai Kamaraj University, Madurai 625 021, Tamil Nadu, India, and cDepartment of Chemistry, Thanthai Hans Roever College, Perambalur 621 212, Tamil Nadu, India. Cg1 is the centroid of the C11–C16 ring. R factor = 0.040; wR factor = 0.112; data-to-parameter ratio = 23.2. C16H15NOS, the thiazolidine ring, which is essentially planar [maximum deviation = 0.071 (2) Å], makes dihedral angles of 88.01 (8) and 87.21 (8) with the terminal phenyl rings. The dihedral angle between the phenyl rings is 49.45 (5). Molecules are linked by a weak intermolecular C—H O hydrogen bond, forming a supramolecular chain along the b axis. The crystal packing is stabilized by a weak C—H interaction

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Crystal data

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