Abstract

In the title salt, C18H15ClNO+·HSO4 −, the quinolinium ring system is approximately planar, with a maximum deviation of 0.028 (2) Å, and forms a dihedral angle of 78.43 (4)° with the attached phenyl ring. A pair of inter­molecular O—H⋯O hydrogen bonds links two hydrogen sulfate anions into a dimer, generating a R 2 2(8) ring motif. Inter­molecular N—H⋯O hydrogen bonds and C—H⋯O contacts link the ions into a three-dimensional network. The structure is further stabilized by C—H⋯π inter­actions

Highlights

  • In the title salt, C18H15ClNO+HSO4, the quinolinium ring system is approximately planar, with a maximum deviation of

  • The structure is further stabilized by C—H interactions

  • For the stability of the temperature controller used for the data collection, see: Cosier & Glazer (1986)

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Summary

Data collection

R factor = 0.044; wR factor = 0.100; data-to-parameter ratio = 16.8. C18H15ClNO+HSO4, the quinolinium ring system is approximately planar, with a maximum deviation of. 0.028 (2) Å, and forms a dihedral angle of 78.43 (4) with the attached phenyl ring. A pair of intermolecular O—H O hydrogen bonds links two hydrogen sulfate anions into a dimer, generating a R22(8) ring motif. H O hydrogen bonds and C—H O contacts link the ions into a three-dimensional network. The structure is further stabilized by C—H interactions

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