Abstract

In addition to the paraelectric-ferroelectric phase transition at T c = + 62°C there is another low T phase transition in the −152 to −165°C range associated with a sudden change in the NQR spectra. The three 35Cl NQR lines observed in the P3 2 ferroelectric phase of (CH 3NH 3)HgCl 3 below T c = 62°C suddenly disappear on cooling below −152°C. No lines could be observed between 152 and −165°C. Below this temperature five 35Cl NQR lines appear and remain down to liquid nitrogen temperature.

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