Abstract

35Cl and 75As NQR spectra have been recorded for six gold(I) chloride complexes with phosphine, arsine and sulfide ligands. Though no 197Au–NQR signals were detected, good 197Au-Mössbauer spectra could be obtained for the same compounds and some homologs. A discussion of the results has shown, that no consistent correlation is evident between the nature of the ligands and the 35Cl and 75As quadrupole coupling constants, 197Au isomeric shifts and quadrupole splittings.

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