Abstract
In the title compound, C13H11N3O2, an intramolecular O—H⋯N hydrogen bond generates an S(7) ring. The dihedral angle between the mean plane of the benzene ring and the imidazolidinone ring is 3.05 (2)°. In the crystal, inversion-related molecules are linked by dual C—H⋯Ocarbonyl hydrogen bonds to form a dimer with an R 2 2(14) graph-set motif. A C—H⋯Ohydroxy interaction links pairs of molecules into another type of cyclic dimer with an R 2 2(18) motif. The molecules are further linked by C—H⋯N interactions to form layers parallel to (001). Offset π–π stacking [3.3877 (8) Å] is observed in the crystal structure, with an interplanar spacing between the planes of neighboring benzene rings of 3.444 (1) Å.
Highlights
In the title compound, C13H11N3O2, an intramolecular O— HÁ Á ÁN hydrogen bond generates an S(7) ring
In the crystal, inversionrelated molecules are linked by dual C—HÁ Á ÁOcarbonyl hydrogen bonds to form a dimer with an R22(14) graph-set motif
The molecules are further linked by C—HÁ Á ÁN interactions to form layers parallel to (001)
Summary
Absorption correction: multi-scan (SADABS; Bruker, 2001) Tmin = 0.811, Tmax = 0.999. C13H11N3O2, an intramolecular O— HÁ Á ÁN hydrogen bond generates an S(7) ring. The dihedral angle between the mean plane of the benzene ring and the imidazolidinone ring is 3.05 (2). In the crystal, inversionrelated molecules are linked by dual C—HÁ Á ÁOcarbonyl hydrogen bonds to form a dimer with an R22(14) graph-set motif. A C—HÁ Á ÁOhydroxy interaction links pairs of molecules into another type of cyclic dimer with an R22(18) motif. The molecules are further linked by C—HÁ Á ÁN interactions to form layers parallel to (001). Offset – stacking [3.3877 (8) A ] is observed in the crystal structure, with an interplanar spacing between the planes of neighboring benzene rings of 3.444 (1) A
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
