Abstract
The title compound, (C16H20N4)3[AgCl4]2, exists as discrete 3,3′-(1,4-phenyldimethylene)bis(1-methylimidazolium) cations and tetrachloroargentate(I) anions, which are linked by C—H⋯Cl hydrogen bonds [C⋯Cl = 3.453 (5)–3.711 (7) Å] and π–π interactions. The asymmetric unit contains one anion, one cation in a general position, and half of a cation which lies on an inversion centre.
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