3-Sulphinyl-5-Amino-1H-1,2,4-Triazoles as Inhibitors of Copper Corrosion

Abstract

A set of electrochemical and full-scale corrosion testing methods demonstrates that 3-sulphinylalkyl-5-amino-1H-1,2,4-triazoles can be used as inhibitors of copper corrosion in neutral chloride solutions and under atmospheric corrosion. It was shown that the inhibition effect of 3-sulphinylalkyl derivatives of 5-amino-1H-1,2,4-triazole increases with the growth of the chain of the additive. By means of the impedance spectroscopy method, the authors determined that the polarisation resistance and the Warburg impedance increases whereas the double-layer capacitance decreased with the growth of the inhibitor chain and the concentration of the inhibitor. In addition, the period when the first signs of corrosion attack appear on the copper plates in the salt spray chamber increased with the growth of the inhibitor chain and its concentrations. The lowest value of this period was measured for 3-sulphinylpropyl derivatives. However, it is still 12 times higher that this value measured without any inhibitors. Full-scale testing in 1% HCl solution showed that the corrosion rate slows down by 10–20 times upon the introduction of the derivatives of 3-sulphinylbutyl and 3-sulphinylpentyl at a concentration of ≥5.00 mM. If the concentration of 3-phenethylsulphinyl is equal to or higher than 1.00 mM, then the protection level is about 85%.