Abstract
The steric structure of the title compound, C19H26O2, has been reported previously [Sondheimer et al. (1960). J. Am. Chem. Soc. 82, 3209–3214] as 14-isoandrosten by optical rotatory dispersion data. The X-ray data of the single crystal shows that ring A has a chair conformation and ring C has a boat conformation. An O—H⋯O hydrogen bond between the hydroxyl group and the carbonyl O atom of an adjacent molecule helps to establish infinite chains along the body diagonal of the unit cell.
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