Abstract
In order to improve the solubility of bimetallic complexes in organic solvents, some new 3,6-bis(2′-pyridyl)pyridazine-based molecules have been synthesised and tested as ligands in platinum(II) organometallic complexes. The reaction of 3,6-bis(2′-pyridyl)-1,2,4,5-tetrazine with terminal acetylenes gives 3,6-bis(2′-pyridyl)-4-substituted pyridazines. Their further reactivity toward (DMSO) 2Pt(CH 3) 2 or (COD)Pt(C 6H 5) 2 (1:1 molecular ratio) is reported. The characterisation of the newly synthesised compound by IR, 1H NMR and electronic spectroscopy is described.
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