Abstract
Geometric characterization of 3,5-dihydroxybenzyl alcohol (DHBA)-based dendrimers has been achieved using molecular mechanics MM+ method and the PM3 semi-empirical molecular orbital theory. Optimization of DHBA-based dendrimer generations 1–5 (DG1–5) showed that DG1–3 have a relatively open structure with no internal spaces of any particular size or shape, while DG4 and 5 assume a more globular structure with well-defined internal cavities. Encapsulation of disperse red 1 (DR1) into the cavities of these dimethylsilyl linked DHBA-based dendrimers led to a blue shift in the λmax of DR1, and transmission electron microscopy (TEM) showed a rectangular shape of dendritic aggregates containing DR1. Catalytic activity of (COD)RhCl(PPh2(CH2)3OH) encapsulated in dendritic aggregates below and above critical aggregation concentration (cac) of generations 1–4 was examined. A significant decrease in catalytic conversion of 1-decene to decane in dendrimer generations 4 upon going from a concentration below cac to above cac was observed.
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