Abstract
The asymmetric unit of the title complex, (C2H6N5)(H3O)[Co(C7H3NO4)2]·C7H5NO4·H2O, contains a CoII ion coordinated by four O atoms and two N atoms from two dipicolinate ligands in a disorted octahedral environment, a protonated triazole molecule, a neutral pyridine-2,6-dicarboxylic acid molecule, a hydroxonium ion and a solvent water molecule. In the crystal, the components are linked into a three-dimensional framework by intermolecular O—H⋯O, N—H⋯O and N—H⋯N and weak C—H⋯O hydrogen bonds. In addition, π–π stacking interactions with centroid–centroid distances in the range 3.4809 (7)–3.8145 (6) Å are observed.
Highlights
The asymmetric unit of the title complex, (C2H6N5)(H3O)[Co(C7H3NO4)2]C7H5NO4H2O, contains a CoII ion coordinated by four O atoms and two N atoms from two dipicolinate ligands in a disorted octahedral environment, a protonated triazole molecule, a neutral pyridine-2,6-dicarboxylic acid molecule, a hydroxonium ion and a solvent water molecule
The components are linked into a threedimensional framework by intermolecular O—H O, N—
For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986)
Summary
H.E.J. Research Institute of Chemistry, International Center for Chemical and Biological Sciences, University of Karachi 75270, Pakistan, bDepartment of Pure and Applied Chemistry, University of Calabar, Calabar, PMB 1115, Nigeria, and cX-ray. Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia
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