Abstract
A synthetic approach to synthesize EDOT and EDOS from a common precursor 5 is reported. The method involves zirconocene dichloride mediated reaction of a common diyne 5 followed by treatment with disulfur dichloride (S(2)Cl(2)) and in situ prepared selenium dichloride (SeCl(2)). The higher lability of alpha-trimethylsilyl group in EDOS compared to EDOT is explained using DFT calculations.
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