Abstract
In the structure of C14H9ClN2O2S [systematic name: 3-(4-chlorophenyl)-4-(phenylsulfanyl)-1,2,3λ5-oxadiazol-3-ylium-5-olate], the central sydnone ring is inclined at angles of 67.49 (10)° to the phenyl ring of the thiophenyl substituent and 52.61 (10)° to the chlorophenyl ring. The compound crystallizes utilizing a network of weak S and Cl-based hydrogen bonds, together with S...Ï, O...Ï and CâH...Ï interactions, forming a three-dimensional structure. In spite of having three planar rings, no ÏâÏ interactions are found.
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