Abstract

The title compound, C16H22N4S2, was obtained by the reaction of sulfur with the corresponding quaternary salt in the presence of K2CO3. It crystallizes with two half-molecules in the asymmetric unit; the complete molecules are generated by inversion symmetry with the central CH2—CH2bonds of the hexane bridges being located on inversion centres. In each molecule, the C6-alkyl chain adopts a typical antiperiplanar conformation and the two heterocyclic rings are oriented antiparallel to each other. In the crystal, molecules are linked by C—H...π interactions, forming layers lying parallel to theacplane.

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