Abstract

3,3'-Dihydroxybenzidine-N,N,N',N'-tetraacetic acid has been prepared and examined as a metallofluorescent indicator in compleximetric titrations. Copper(II) and lead(II) are determined by titration with EDTA in the presence of the indicator, the blue fluorescence of which is restored at the end-point. Manganese, zinc, cobalt and cadmium can also be determined if a dyestuff such as Rhodamine B is present along with the indicator.

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