Abstract
In the title complex, [Ni(NO3)2(C14H16N6O2)]·H2O, the NiII atom, lying on a twofold rotation axis, is coordinated by a tetradentate 3,3′-{(1E,1′E)-1,1′-[ethane-1,2-diylbis(azan-1-yl-1-ylidene)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide ligand and two mutually trans monodentate nitrate anions in a distorted octahedral geometry. The lattice water molecule is located on a twofold rotation axis. The complex molecules are linked by the water molecules through O—H⋯O hydrogen bonds into a chain along [001]. Further C—H⋯O hydrogen bonds lead to the formation of a three-dimensional network.
Highlights
In the title complex, [Ni(NO3)2(C14H16N6O2)]H2O, the NiII atom, lying on a twofold rotation axis, is coordinated by a tetradentate 3,30 -{(1E,10 E)-1,10 -[ethane-1,2-diylbis(azan-1-yl1-ylidene)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide ligand and two mutually trans monodentate nitrate anions in a distorted octahedral geometry
The lattice water molecule is located on a twofold rotation axis
The complex molecules are linked by the water molecules through O—H O hydrogen bonds into a chain along [001]
Summary
Rint = 0.034 a College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, People’s Republic of China, and bDepartment of Chemistry, Faculty of Education, University of Khartoum, Sudan. R factor = 0.032; wR factor = 0.070; data-to-parameter ratio = 12.1. In the title complex, [Ni(NO3)2(C14H16N6O2)]H2O, the NiII atom, lying on a twofold rotation axis, is coordinated by a tetradentate 3,30 -{(1E,10 E)-1,10 -[ethane-1,2-diylbis(azan-1-yl1-ylidene)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide ligand and two mutually trans monodentate nitrate anions in a distorted octahedral geometry. The lattice water molecule is located on a twofold rotation axis. The complex molecules are linked by the water molecules through O—H O hydrogen bonds into a chain along [001]. Further C—H O hydrogen bonds lead to the formation of a three-dimensional network
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