Abstract

AbstractA base‐catalyzed novel [3+2] cycloaddition reaction between arylidene‐1‐phenyl succinimides and alkylidene acenaphthylenones is carried out to access succinimide substituted spiro[acenaphthylenone‐cyclopentane]fused scaffolds with high regio‐ and stereo‐selectivity under mild conditions. The reaction of alkylidene acenaphthylenones with 1,4‐benzoxazinone derivatives under the influence of environmentally benign iodine afforded polyheterocyclic compounds embedded with pyrrole moiety. This metal‐free synthesis is highly efficient and atom economic and the protocol obviates column chromatography. The products are isolated by simple decantation followed by washing with solvent.

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