2D Spatially Periodic Architectures via the Drying of 1D Holographically Photopatterned Polymer Solutions

Abstract

We demonstrate an efficient and versatile method for selectively generating 1D and 2D periodic polymer structures in the submicron to tens of micron range by the directed drying of 1D photopatterned polymer solutions. Ultraviolet (UV) holographic lithography (Xia et al. Chem. Rev. 1999, 99, 1823-1848) is initially used to create 1D periodic cross-link and density variations in the polymer/volatile solvent solutions. These variations act as anisotropic barriers (walls) that direct the subsequent solvent evaporation process. Somewhat akin to directional drying (Allain and Limat Phys. Rev. Lett. 1995, 74, 2981-2984) and directional solidification (Pelc, P. Dynamics of Curved Fronts; Academic Press: San Diego, CA, 1988) experiments, the drying exhibits channel-like interface propagation behavior. The combination of the instabilities and minimization of the interface area during drying can be effectively used to produce larger scale 2D pseudohexagonal polymer-strut structures, or by the addition of a monomeric component to the polymer solution, the instabilities can be suppressed, resulting in the formation of 1D linear gratings.