Abstract
Cocrystallization of melamine with organic sulfonic acids (1,5-naphthalenedisulfonic acid and 4,4′-biphenyldisulfonic acid) gives rise to 2D porous organic frameworks. Each 2D framework has a different channel size according to the length of the organic sulfonic acids. The adsorption of various liquid alcohols (1-butanol, 1-hexanol, 1-octanol, 1-decanol, 1-dodecanol, tert-butanol, and 2-ethyl-1-hexanol) into the channels in the single-crystal to single-crystal (SCSC) mode was effective for each channel. The tailor-made metal-free organic pores presented herein can be useful components of a practical template for a 3D structure determination of various liquid alcohols.
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