2D network coordination polymers of lanthanide with N-(2-pyridylmethyl)iminodiacetic acid: Hydrothermal syntheses, crystal structures and luminescent properties

Abstract

Six lanthanide two-dimensional network coordination polymers with the general formula of [Ln(pmida)(NO 3)(H 2O)] n , where Ln = La ( 1), Nd ( 2), Sm ( 3), Gd ( 4), Dy ( 5), Er ( 6) and pmida 2− = N-(2-pyridylmethyl)iminodiacetate, have been synthesized by hydrothermal process and characterized by elemental analysis, Infrared spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction. All crystals are isostructural and crystallize in the monoclinic space group P2 1/ a. The lanthanide(III) ion is nine-coordinated in a geometry of distorted tricapped trigonal prism by two N atoms and two O atoms from one pmida 2− ligand, two bridging carboxylate O atoms from other two pmida 2− ligands, two O atoms of a bidentate chelating nitrate and a O atom of a coordinated water molecule. The luminescent properties of [Sm(pmida)(NO 3)(H 2O)] n ( 3) and [Dy(pmida)(NO 3)(H 2O)] n ( 5) were investigated.