2D Correlation Analysis of the Continuum in Single Molecule Surface Enhanced Raman Spectroscopy

Abstract

The role and the nature of the continuum in Surface Enhanced Raman Spectroscopy (SERS) are unclear. Here, two-dimensional (2D) covariance and correlation analysis is applied to single molecule SERS spectra on silver colloids with and without rhodamine 6G (native colloid). The resulting 2D covariance and correlation maps show that the sharp molecular Raman peaks from rhodamine 6G and the molecule responsible for the SERS peaks from the native colloid are correlated to different continua even though both continua are present in each data set. This suggests that two distinct active sites on the silver colloids produce the two different continua, and that each site has some molecular specificity.