2D and 3D Zn(II) coordination polymers based on 4′-(Thiophen-2-yl)-4,2′:6′,4′'-terpyridine: Structures and features of sorption behavior

Alexander S Zaguzin,Ghodrat Mahmoudi,Taisia S Sukhikh,Ilyas F Sakhapov,Dmitry A Zherebtsov,Fedor I Zubkov,Karina S Valchuk,Maxim N Sokolov,Vladimir P Fedin,Sergey A Adonin

doi:10.1016/j.molstruc.2022.132459

2D and 3D Zn(II) coordination polymers based on 4′-(Thiophen-2-yl)-4,2′:6′,4′'-terpyridine: Structures and features of sorption behavior

Alexander S Zaguzin, Ghodrat Mahmoudi + Show 8 more

https://doi.org/10.1016/j.molstruc.2022.132459

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Journal: Journal of Molecular Structure	Publication Date: Jan 20, 2022
Citations: 5

Affiliation: University of Maragheh, Peoples' Friendship University of Russia, Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, South Ural State University

#2D Coordination Polymer #I2 Absorption + Show 8 more

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Abstract

Reactions of Zn(II) nitrate, 4′-(Thiophen-2-yl)-4,2′:6′,4′'-terpyridine (ThioTerPy) and terephtalic (bdc) or 2-iodoterephtalic (2-I-bdc) acids result in 2D coordination polymer [Zn2bdc(ThioTerPy)2(OH)2] (1) or 3D metal-organic framework [Zn(2-I-bdc)(ThioTerPy)] (2), respectively. Both compounds were characterized by X-ray diffractometry. For 2, I2 absorption, as well as selectivity of sorption of different organic substrates from mixtures was studied.

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