Abstract

This chapter examines the case of thermal migration through a barrier. This leads to three specifically non-equilibrium quantities called “quantities of transport.” They are the entropy of transport, the energy of transport, and the heat of transport. The latter is a true thermodynamic quantity, which can be determined by calorimetric measurements in steady-state migration. Furthermore, chapter establishes the relation between entropy and energy transport. The same result is obtained for the expression of energy of transport, regardless of the representation selected. This served to demonstrate the equivalence of the representations by the pivotal equations of linear steady-state thermodynamics and parallels the equivalence of the representations by the cardinal equations of the equilibrium theory.

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