Abstract
The aluminum coordination state in bismuth doped silica glass, which has new broad infrared emission at 1.3 μm regions, was investigated by using 27Al NMR, and it is demonstrated that 6-fold coordinated aluminum ions with corundum structure are dominant in bismuth doped silica glass until Bi 2O 3 concentrations of 1.0 mol% with Al 2O 3. The aluminum ion efficiently affects the creation of a Bi luminescent center at an intensity of Bi 2O 3 (1.0 mol%)–Al 2O 3 (2.3 mol%)–SiO 2 (96.7 mol%); the sample is three orders of magnitude larger than the Bi 2O 3 (1.0 mol%)–SiO 2 (99.0 mol%) sample. Aluminum ions with corundum structure in silica glass have a very important role for the configuration of peculiar Bi luminescent centers.
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